Salen相关论文
在混合有机溶剂中,通过双隔室多齿Salen型配体(H2L)与乙酸钴(Ⅱ)自组装反应,成功培养了一个新颖的双核八面体钴(Ⅲ)-Salen配合物单......
Supramolecular Polymer Networks with Enhanced Mechanical Properties:The Marriage of Covalent Polymer
Supramolecular polymer networks (SPNs) have always been the focus of research due to their novel features of good proces......
Salen类化合物是配位化学中最具有代表性的优势配体之一,作为均相催化剂在有机合成转化中占据非常重要的地位。共价有机框架材料（CO......
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PM-PP-14:Aluminum-Salen Complexes as Host Materials for Phosphorescent Organic Light-Emitting Diodes
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Coordination polymer have drawn much attention in recent years because of their potential application in magnetism,l......
composites poly [Ni (salen )] 并且多围的碳 nanotube (MWCNT ) 被脉搏 potentiostatic 综合方法。composites 被扫描电子显微镜......
Recoverable Mn^Ⅲ（salen） supported on diamine modified zirconium poly（styrene-isopropenyl phosphonate
Chiral Mn Ⅲ (salen) (Jacobsen's catalyst) was axially immobilized onto a new type of organic polymer-inorganic hybr......
Recoverable Mn~Ⅲ (salen) supported on diamine modified zirconium poly(styrene-isopropenyl phosphonat
Chiral Mn Ⅲ (salen) (Jacobsen’s catalyst) was axially immobilized onto a new type of organic polymer-inorganic hybrid ......
为了比较不同价态的金属-Salen配合物与DNA的作用,按文献方法,合成了以N,N’-双(2-羟基-1-萘甲醛)缩邻苯二胺这种Salen配体,Salen......
以对苯二甲酰氯为交联剂,利用界面聚合法合成了链状Salen型高分子席夫碱金属配合物PLSBM(M:CoⅡ,MnⅡ,ZnⅡ,CuⅡ),通过元素分析、......
A kind of novel biopolymer antioxidant (BSA/HOSalenM, M=Co, Mn, Zn) is prepared with conjugation, which increases the an......
A one pot three‐component coupling reaction of phenylacetylene, aldehyde, and amine derivatives in the presence of Cu(I......
Ring-opening Copolymerization of Cyclohexene Oxide and Maleic Anhydride Catalyzed by Mononuclear [Zn
From the self-assembly of the typical Salen-type Schiff-base ligand H2L and Zn(OAc)2·2H2O in the molar ratio of 1:1 or ......
Electropolymerization of Ni(salen) on carbon nanotube carrier as a capacitive material by pulse pote
The composites of poly[Ni(salen)] and multi-walled carbon nanotube(MWCNT) were synthesized by pulse potentiostatic metho......
使用不同空间位阻的苯氧链接手臂修饰的聚(苯乙烯基-苯乙烯膦酸)-磷酸氢锆轴向固载手性MnIII(Salen)催化剂(Cat1–Cat3),随后在间......
参照文献方法,合成了N,N’-双(2-羟基-1-萘甲醛)缩邻苯二胺、乙二胺和1,3-丙二胺的3种Salen配体及其与Mn(Ⅲ)、Co(Ⅲ)形成的6种配......
Salen型金属配合物具有结构多样、合成相对简单、廉价和应用广泛等诸多优点,被广泛用在许多研究领域中,尤其作为催化剂在有机合成......
为了研究Salen-卟啉配合物催化氧化木素模型物,我们合成了Salen-卟啉配合物(Zn PSC6).用由Zn PSC6、吡啶(联吡啶)、H202、Na OH组......
制备了一系列通过苯氧基修饰的聚(苯乙烯-异丙烯膦酸)磷酸氢锆(ZPS-IPPA)轴向固载手性MnⅢ(Salen)催化剂,并将其应用于苯乙烯的环......
通过1,3-苯二胺缩邻香兰素和Ln(acac)3·H2O(Ln=Ce,Eu)反应,合成了2种双核稀土配合物[Ce2L(acac)4(CH3OH)]2·2CH2Cl2(1)和[Eu2L(a......
将原位生成的Salen稀土金属催化剂直接用于催化消旋环氧氯丙烷的水解动力学拆分,考察了温度、金属中心、反应时间、催化剂负载量、......
Schriff碱是由醛和氨缩聚而形成的一种碱类,由于其特殊的分子结构,可与某些金属反应,生成M-Salen配合物,该类配合物具有更高的活性......
合成了一种水溶性Salen配合物Cu(SalenSO3)Na2·3H2O,采用紫外可见光谱法研究了其作为过氧化氢模拟酶催化过氧化氢氧化对苯二酚的......
在过去的十多年中,由过渡金属(Cr,Ni,Co,Ru,Mn)参与催化的烯烃环氧化反应受到人们的大量关注,制备的环氧化物中间体被广泛应用于医......
通过配体邻苯二胺缩邻香兰素(H_2L)与Dy(NO_3)_3·6H_2O反应,合成了类Salen稀土配合物[Dy_5L_4(NO_3)_4(CH_3O)_2]·NO_3·3CH_2Cl......
Dicyanide building block cis-Fe(phen)_2(CN)_2 and [Mn~Ⅲ(salen)](ClO_4) have been used to design and synthesize a cyanid......
合成并表征了一种新型高效的席夫碱钴催化剂,其用于催化二氧化碳与环氧丙烷的聚合,得到了窄相对分子质量分布的聚碳酸酯.另外,系统......
细胞内微黏度是描述细胞状态的重要物理参数,与物质转运和信号转导等一系列扩散控制的生理过程密切相关.构筑对细胞内微黏度响应灵......
随着全球“温室效应”和能源危机的加剧,近几年二氧化碳作为一种丰富、无毒、廉价的碳一原料广受关注.目前,在温和条件下实现二氧......
以4-硝基苯乙酮为原料,经溴化、还原和闭环反应生成外消旋的4-硝基环氧苯乙烷,经手性(R,R)-Salen-Co(Ⅲ)催化剂催化水解动力学拆分......
Secondary alcohols were catalytically oxidized with diacetoxyiodobenzene as oxidant in the presence of salen- Mn(III) c......
The molecular recognition behavior of the chiral salen-metalcomplexes towards guest molecules, such as imidazole deriva......
Salen是最简单的Schiff碱之一。最近发现,其Fe(Ⅲ)的配合物Fe(Salen)NO_3能与仲胺作用,并很快生成致癌物质亚硝胺。另一方面,一些......
TiCl_3·3THF与Salen-Na_2在THF中反应得到标题化合物。在混合溶剂中培养出单晶,用X射线衍射法测定了结构。晶体属正交晶系,空间群......
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Ethyleneoligomerizationand polymerizationcatalyzedbyα diiminePd (Ⅱ) orNi (Ⅱ) complexeshavebe......
具有生物活性的铁Salen络合物通过自由配体法在高硅沸石MCM 2 2的“瓶”状超笼中合成 ,该笼具有 1 82nm的高度 ,0 71nm的直径 ,中......
采用自由配体法在 β沸石的空腔内合成了Fe(Ⅱ )Salen络合物。XRD ,SEM ,TG DTA ,UV Vis和元素分析等物理化学方法的分析结果表明 ......
Inorganic ChemistrySynthesis of Silica Molecular Sieves and Their U se in Fine Chemicals 14 ( 1) ,0 0 1The Research Prog......
Several new chiral organogallium and indium complexes with chiral Salen (1 and 2) as anxciliary ligands have been synthe......
